Tag Archives: PPP-EFM

Signal Origin of Electrochemical Strain Microscopy and Link to Local Chemical Distribution in Solid State Electrolytes

Solid state electrolytes (SSEs) are interesting materials that could potentially replace the currently used organic electrolytes in lithium‐ion batteries (LIBs). *

Electrochemical strain microscopy (ESM), a research technique based on atomic force microscopy (AFM), was developed to locally probe ion movement in electrodes based on electro-chemo-mechanical coupling measure through the AFM cantilever deflection. It can be used to characterize Li-ion mobility in energy materials with extremely high spatial resolution. *

The main challenge with ESM is its nonquantitative nature due to complex AFM cantilever dynamics in contact mode when performed on resonance as well as signal contribution that are not necessarily related to ions such as electrostatic forces.*

In the article “ Signal Origin of Electrochemical Strain Microscopy and Link to Local Chemical Distribution in Solid State Electrolytes “ Nino Schön, Roland Schierholz, Stephen Jesse, Shicheng Yu, Rüdiger‐A. Eichel, Nina Balke and Florian Hausen investigate the exact signal formation process of electrochemical strain microscopy (ESM) when it is applied on sodium super ionic conductor (NASCIO)-type solid state electrolytes containing Na- and Li-ions.*

In their research the authors correlatively use various scanning probe microscopy (SPM) based microscopy techniques together with scanning electron microscopy (SEM) and Energy Dispersive X-Ray Spectroscopy ( EDX ) at identical positions of the solid state electrolyte LATP.*

They find that changes in the dielectric properties are responsible for the detected contrast in the deflection of the AFM cantilever instead of a physical volume change as a result of Vegard’s Law. The AFM cantilever response is strongly reduced in areas of high sodium content which is attributed to a reduction of the AFM tip-sample capacitance in comparison with areas with high lithium content.*

This is the first time a direct link between electrostatic forces in contact mode and local chemical information is demonstrated on SSEs. The results presented in the article open up the possibility to learn more since dielectric properties are sensitive to subtle changes in local chemical composition.*

NANOSENSORS conductive Platinum-Iridium coated PointProbe® Plus PPP-EFM AFM probes were primarily used in the research for this article.

Figure 1 from Nino Schön et al. «Signal Origin of Electrochemical Strain Microscopy and Link to Local Chemical Distribution in Solid State Electrolytes”:
a) Topography, b) deflection error, and c) corresponding cantilever deflection change (Dac) map of a 30 µm × 30 µm area of LATP. d) Noncontact EFM amplitude map in the same area.
NANOSENSORS conductive platinum-iridium coated PointProbe Plus PPP-EFM AFM probes were used.
Figure 1 from Nino Schön et al. «Signal Origin of Electrochemical Strain Microscopy and Link to Local Chemical Distribution in Solid State Electrolytes”:
a) Topography, b) deflection error, and c) corresponding cantilever deflection change (Dac) map of a 30 µm × 30 µm area of LATP. d) Noncontact EFM amplitude map in the same area.

*Nino Schön, Roland Schierholz, Stephen Jesse, Shicheng Yu, Rüdiger‐A. Eichel, Nina Balke, Florian Hausen
Signal Origin of Electrochemical Strain Microscopy and Link to Local Chemical Distribution in Solid State Electrolytes
Small Methods, Early View, Online Version of Record before inclusion in an issue 2001279
DOI: https://doi.org/10.1002/smtd.202001279

Please follow this external link to read the full article: https://onlinelibrary.wiley.com/doi/10.1002/smtd.202001279

Open Access The article “Signal Origin of Electrochemical Strain Microscopy and Link to Local Chemical Distribution in Solid State Electrolytes” by Nino Schön, Roland Schierholz, Stephen Jesse, Shicheng Yu, Rüdiger‐A. Eichel, Nina Balke, Florian Hausen is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

Engineering work function of graphene oxide from p to n type using a low power atmospheric pressure plasma jet

Graphene, since its discovery in 2004 has attracted enormous interest due to its physical and chemical properties, and wide applications. *

Graphene oxide (GO) has emerged as an attractive alternative to graphene due to low cost, large scale production and solution processability. GO is prepared by oxidative exfoliation of graphite.*

The work function is a fundamental electronic property of a material and can be used to interpret the relative position of the Fermi level.*

For efficient transport of electrons or holes in a heterojunction device, the work function of the materials plays a crucial role, since work function determines how the bands will align at the contacts.*

Recently there has been an increased interest in applications of GO for interfacial layers and transparent electrode materials in optoelectronic devices e.g. liquid crystal displays (LCDs), organic light emitting diodes (OLEDs), touch screens, dye-sensitized solar cells (DSSCs) and as supercapacitor electrodes. Tuning the work function of GO is key to achieving high performance devices. *

In the article “Engineering work function of graphene oxide from p to n type using a low power atmospheric pressure plasma jet” by Avishek Dey, Paheli Ghosh, James Bowen, Nicholas St. J. Braithwaite and Satheesh Krishnamurthy, the authors demonstrate doping graphene oxide (GO) films using a low power atmospheric pressure plasma jet (APPJ) with subsequent tuning of the work function.*

The surface potential of the plasma functionalized GO films could be tuned by 120 ± 10 mV by varying plasma parameters. *

Scanning Kelvin probe microscopy ( SKPM ) also known as Kelvin probe force microscopy ( KPFM ) measurements were carried out to realize changes in work function of the GO films with plasma functionalization.*

NANOSENSORS™ PointProbe® Plus PPP-EFM AFM probes with a platinum iridium coating were used to perform surface potential measurements. *

The Kelvin probe studies showed that the bonding configuration can influence the work function of GO. Pyridinic nitrogen transforms GO to p-type while graphitic nitrogen increases the electron density of GO and transforming it to n type. Pointing to the fact that a low power APPJ can effectively tune the work function of GO and hence the conductivity. *

The findings presented in the article are extremely useful in fabricating heterojunction devices like sensors and optoelectronic devices where band structure alignment is key to device performance when GO is used as a charge transport layer. This technique can be extended to other known 2D systems.*

Fig. 10 (a) from “Engineering work function of graphene oxide from p to n type using a low power atmospheric pressure plasma jet” by Avishek Dey et al.:

a) KPFM surface potential map of reference GO thin film ( please have a look at https://pubs.rsc.org/image/article/2020/CP/c9cp06174f/c9cp06174f-f10_hi-res.gif for the full figure.)
Figure 10 (a) from “Engineering work function of graphene oxide from p to n type using a low power atmospheric pressure plasma jet” by Avishek Dey et al.:

a) KPFM surface potential map of reference GO thin film ( please have a look at https://pubs.rsc.org/image/article/2020/CP/c9cp06174f/c9cp06174f-f10_hi-res.gif for the full figure.)

*Avishek Dey, Paheli Ghosh, James Bowen, Nicholas St. J. Braithwaite and Satheesh Krishnamurthy
Engineering work function of graphene oxide from p to n type using a low power atmospheric pressure plasma jet
Physical Chemistry Chemical Physics, 2020, 22, 7685-7698
DOI: 10.1039/C9CP06174F

Please follow this external link for the full article: https://pubs.rsc.org/en/content/articlehtml/2020/cp/c9cp06174f

Open Access: The article “Engineering work function of graphene oxide from p to n type using a low power atmospheric pressure plasma jet” by Avishek Dey, logoa, Paheli Ghosh, James Bowen, Nicholas St. J. Braithwaite and Satheesh Krishnamurthy is licensed under a Creative Commons Attribution 3.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/3.0/.

Ferroelectricity-free lead halide perovskites

In the recent publication “Ferroelectricity-free lead halide perovskites” Andrés Gómez, Qiong Wang, Alejandro R. Goñi, Mariano Campoy-Quilesa and Antonio Abate describe how they employed direct piezoelectric force microscopy ( DPFM ) to examine whether or not lead halide perovskites exhibit ferroelectricity.*

Their article aims to provide a deeper understanding of the fundamental physical properties of the organic–inorganic lead halide perovskites and solves a longstanding dispute about their non-ferroelectric character: an issue of high relevance for optoelectronic and photovoltaic applications.*

In the course of their research in which besides using DPFM, they also employed piezoelectric force microscopy ( PFM ) and electrostatic force microscopy ( EFM ), they could demonstrate the non-ferroelectricity of lead halide perovskites. *

The PFM images were acquired using a PtIr coated NANOSENSORS PPP-EFM AFM probe.

Fig. 5 from “Ferroelectricity-free lead halide perovskites” by Andrés Gómez et al.: Scheme of the three AFM modes DPFM (a), EFM (b) and PFM (c) with the measurement results of the MAPbI3 perovskite at a film thickness of 152 nm ((i): scanning from left to right, and (ii): scanning from right to left for DPFM measurements; and (iii) and (iv) for EFM and PFM measurements, respectively), 218 nm ((v): scanning from left to right, and (vi): scanning from right to left for DPFM measurements; and (vii) and (viii) for EFM and PFM measurements, respectively), and 400 nm ((ix): scanning from left to right, and (x): scanning from right to left for DPFM measurements; and (xi) and (xii) for EFM and PFM measurements, respectively). Insets given in (iii), (vii), and (xi) are the topography channel of EFM images of the samples.

*Andrés Gómez, Qiong Wang, Alejandro R. Goñi, Mariano Campoy-Quilesa, Antonio Abate
Ferroelectricity-free lead halide perovskites
Energy Environ. Sci., 2019, Advance Article
doi: 10.1039/C9EE00884E

Please follow this external link to the full article: https://pubs.rsc.org/en/content/articlelanding/2019/ee/c9ee00884e#!divAbstract

Open Access: The article “Ferroelectricity-free lead halide perovskites” by Andrés Gómez, Qiong Wang, Alejandro R. Goñi, Mariano Campoy-Quilesa and Antonio Abate is licensed under a Creative Commons Attribution 3.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. To view a copy of this license, visit https://creativecommons.org/licenses/by/3.0/