{"id":4393,"date":"2020-04-28T14:52:52","date_gmt":"2020-04-28T11:52:52","guid":{"rendered":"https:\/\/nanosensors.com\/blog\/nontoxic-pyrite-iron-sulfide-nanocrystals-as-second-electron-acceptor-in-ptb7pc71bm-based-organic-photovoltaic-cells\/"},"modified":"2023-03-15T14:51:33","modified_gmt":"2023-03-15T12:51:33","slug":"nontoxic-pyrite-iron-sulfide-nanocrystals-as-second-electron-acceptor-in-ptb7pc71bm-based-organic-photovoltaic-cells","status":"publish","type":"post","link":"https:\/\/www.nanosensors.com\/blog\/nontoxic-pyrite-iron-sulfide-nanocrystals-as-second-electron-acceptor-in-ptb7pc71bm-based-organic-photovoltaic-cells\/","title":{"rendered":"Nontoxic pyrite iron sulfide nanocrystals as second electron acceptor in PTB7:PC71BM-based organic photovoltaic cells"},"content":{"rendered":"\n<p>Iron disulfide ( FeS2 ) is a\nnatural earth-abundant and nontoxic material with possible applications in\nlithium batteries, transistors or photovoltaic (PV) devices. According to the\nanalysis carried out by Wadia et al., among 23 semiconducting materials, FeS2\nis the best candidate for the development of large-scale solar cells at low\ncost (&lt;2 \u00d7 10\u22126 \u00a2\/W). Furthermore, FeS2 exhibits excellent optoelectronic\nproperties such as a band gap of 0.8 to 1.38 eV, a high optical absorption\ncoefficient (2 \u00d7 105 cm\u22121), high carrier mobility (2 to 80 cm2\/Vs) and a large\ncharge carrier lifetime (200 ps). Therefore, FeS2 nanoparticles (NPs) can be a\ngood alternative for PV applications.*<\/p>\n\n\n\n<p>In \u201c<em>Nontoxic\npyrite iron sulfide nanocrystals as second electron acceptor in\nPTB7:PC71BM-based organic photovoltaic cells<\/em> \u201c Olivia Amarg\u00f3s-Reyes,\nJos\u00e9-Luis Maldonado, Omar Mart\u00ednez-Alvarez, Mar\u00eda-Elena Nicho, Jos\u00e9\nSantos-Cruz, Juan Nicasio-Collazo, Irving Caballero-Quintana and Concepci\u00f3n Arenas-Arrocena\nreport the synthesis of nontoxic pyrite iron sulfide ( FeS2 ) nanocrystals\n(NCs) using a two-pot method. Moreover, they study the influence of these NCs\nincorporated into the PTB7:PC71BM active layer of bulk-heterojunction ternary\norganic photovoltaic ( OPV ) cells.*<\/p>\n\n\n\n<p>The AFM roughness images presented in this article were acquired in dynamic force mode using NANOSENSORS\u2122 <a href=\"https:\/\/www.nanosensors.com\/uploads\/media\/files\/0001\/05\/9a1ca80f36ec88ce17a91c72296d2ad2067f0f91.pdf\" target=\"_blank\" rel=\"noreferrer noopener\" aria-label=\"PointProbe\u00ae Plus (opens in a new tab)\">PointProbe\u00ae Plus<\/a> <a href=\"https:\/\/www.nanosensors.com\/pointprobe-plus-non-contact-tapping-mode-long-cantilever-au-coating-afm-tip-PPP-NCLAu\" target=\"_blank\" rel=\"noreferrer noopener\" aria-label=\"PPP-NCLAu (opens in a new tab)\">PPP-NCLAu<\/a> AFM probes.<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img decoding=\"async\" src=\"https:\/\/nanosensors.com\/blog\/wp-content\/uploads\/2022\/11\/figure-7-from-Nontoxic-pyrite-iron-sulfide-nanocrystals-as-second-electron-acceptor-in-PTB7_PC71BM-based-organic-photovoltaic-cells-2.jpg\" alt=\"Figure 7 from \u201cNontoxic pyrite iron sulfide nanocrystals as second electron acceptor in PTB7:PC71BM-based organic photovoltaic cells\u201d shows the 2D (left) and 3D (right) AFM images of the OPVs with different concentrations of FeS2 recorded in the noncontact mode. The roughness of the OPV surface is increased gradually as the FeS2 concentration increases (Table 1 and Figure 7), such that traps for the charge carriers could occur and the leakage current could increase. Because of the FeS2 agglomerates, the OPV parameters tend to decrease, free charges cannot be efficiently extracted. This effect is most prominent for the OPV cells with 1% of FeS2 (Figure 7 and Supporting Information File 1, Figure S2d).\" class=\"wp-image-2280\"\/><figcaption>  Figure 7 from \u201cNontoxic pyrite iron sulfide nanocrystals as second electron acceptor in PTB7:PC71BM-based organic photovoltaic cells\u201d by Olivia Amarg\u00f3s-Reyes et al.:<br> 2D (left) and 3D (right) AFM images of the OPVs with different concentrations of FeS2<br> (a) 0.0 wt %, b) 0.25 wt %, c) 0.5 wt % and d) 1.0 wt %) recorded in noncontact mode. <\/figcaption><\/figure>\n\n\n\n<p>*Olivia Amarg\u00f3s-Reyes, Jos\u00e9-Luis Maldonado,\nOmar Mart\u00ednez-Alvarez, Mar\u00eda-Elena Nicho, Jos\u00e9 Santos-Cruz, Juan\nNicasio-Collazo, Irving Caballero-Quintana and Concepci\u00f3n Arenas-Arrocena<br>\n<strong>Nontoxic pyrite iron sulfide nanocrystals as second electron acceptor in PTB7:PC71BM-based\norganic photovoltaic cells<\/strong><br>\nBeilstein Journal of . Nanotechnology 2019, 10, 2238\u20132250.<br>\nDOI: doi:10.3762\/bjnano.10.216<\/p>\n\n\n\n<p>Please follow this external link to read the full article: <a href=\"https:\/\/www.beilstein-journals.org\/bjnano\/articles\/10\/216#R65\" target=\"_blank\" rel=\"noreferrer noopener\" aria-label=\"https:\/\/www.beilstein-journals.org\/bjnano\/articles\/10\/216#R65  (opens in a new tab)\">https:\/\/www.beilstein-journals.org\/bjnano\/articles\/10\/216#R65 <\/a><\/p>\n\n\n\n<p>Open Access: The article \u201c<em>Nontoxic pyrite iron sulfide nanocrystals as second electron acceptor in PTB7:PC71BM-based organic photovoltaic cells<\/em>\u201d by Olivia Amarg\u00f3s-Reyes, Jos\u00e9-Luis Maldonado, Omar Mart\u00ednez-Alvarez, Mar\u00eda-Elena Nicho, Jos\u00e9 Santos-Cruz, Juan Nicasio-Collazo, Irving Caballero-Quintana and Concepci\u00f3n Arenas-Arrocena is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article\u2019s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article\u2019s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http:\/\/creativecommons.org\/licenses\/by\/4.0\/. <\/p>\n","protected":false},"excerpt":{"rendered":"<p>Iron disulfide ( FeS2 ) is a natural earth-abundant and nontoxic material with possible applications in lithium batteries, transistors or photovoltaic (PV) devices. According to the analysis carried out by Wadia et al., among 23 semiconducting materials, FeS2 is the best candidate for the development of large-scale solar cells at low cost (&lt;2 \u00d7 10\u22126&hellip;&nbsp;<a href=\"https:\/\/www.nanosensors.com\/blog\/nontoxic-pyrite-iron-sulfide-nanocrystals-as-second-electron-acceptor-in-ptb7pc71bm-based-organic-photovoltaic-cells\/\" class=\"\" rel=\"bookmark\">Read More &raquo;<span class=\"screen-reader-text\">Nontoxic pyrite iron sulfide nanocrystals as second electron acceptor in PTB7:PC71BM-based organic photovoltaic cells<\/span><\/a><\/p>\n","protected":false},"author":2,"featured_media":4394,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"neve_meta_sidebar":"","neve_meta_container":"","neve_meta_enable_content_width":"","neve_meta_content_width":0,"neve_meta_title_alignment":"","neve_meta_author_avatar":"","neve_post_elements_order":"","neve_meta_disable_header":"","neve_meta_disable_footer":"","neve_meta_disable_title":"","footnotes":""},"categories":[16],"tags":[17,18,448,339,398,19,460,465,129,459,182,440,462,461,435,312,37,27,458,463,464,60,343,109,107,340,447,114,442,400,342],"class_list":{"0":"post-4393","1":"post","2":"type-post","3":"status-publish","4":"format-standard","5":"has-post-thumbnail","6":"hentry","7":"category-science-technology","8":"tag-afm-probes","9":"tag-afm-tips","10":"tag-afm","13":"tag-atomic-force-microscopy","14":"tag-fes2","15":"tag-fes2-nanoparticles","16":"tag-gold-coated-pointprobe-plus-afm-tips","17":"tag-iron-disulfide","18":"tag-nanoparticles","19":"tag-opv","20":"tag-opvs","21":"tag-organic-photovoltaic-cells","22":"tag-organic-solar-cells","23":"tag-photovoltaics","24":"tag-pointprobe-plus","25":"tag-pointprobe-plus-ppp","26":"tag-ppp-nclau","27":"tag-ptb7","28":"tag-pyrite","29":"tag-scanning-probe-microscopy","30":"tag-solar-cells","31":"tag-spm-probes","32":"tag-spm-tips","33":"tag-spm","35":"tag-tapping-mode","36":"tag-442","37":"tag-400","38":"tag-342"},"_links":{"self":[{"href":"https:\/\/www.nanosensors.com\/blog\/wp-json\/wp\/v2\/posts\/4393","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.nanosensors.com\/blog\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.nanosensors.com\/blog\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.nanosensors.com\/blog\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/www.nanosensors.com\/blog\/wp-json\/wp\/v2\/comments?post=4393"}],"version-history":[{"count":0,"href":"https:\/\/www.nanosensors.com\/blog\/wp-json\/wp\/v2\/posts\/4393\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.nanosensors.com\/blog\/wp-json\/wp\/v2\/media\/4394"}],"wp:attachment":[{"href":"https:\/\/www.nanosensors.com\/blog\/wp-json\/wp\/v2\/media?parent=4393"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.nanosensors.com\/blog\/wp-json\/wp\/v2\/categories?post=4393"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.nanosensors.com\/blog\/wp-json\/wp\/v2\/tags?post=4393"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}